Re: out of curiosity
I'm guessing (so hopefully someone who knows will chip in) but as I understand it, a solid core would be slowly (as in, a billion years or so) crystalising out of the melt (the outer core) and so it is to be expected that it will show some selectivity in what atoms it permits in the emerging crystal structure.
Alternatively, perhaps it is a mixture but it is so predominantly iron and nickel that geologists don't sweat the details. Hmm ... now I'm curious, too. (Trundles off to https://en.wikipedia.org/wiki/Inner_core...)
"Based on the relative prevalence of various chemical elements in the Solar System, the theory of planetary formation, and constraints imposed or implied by the chemistry of the rest of the Earth's volume, the inner core is believed to consist primarily of a nickel-iron alloy. Pure iron was found to be denser than the core by approximately 3%, implying the presence of light elements in the core (e.g. silicon, oxygen, sulfur) in addition to the probable presence of nickel.[11]
Further, if the primordial and mostly fluid (still forming) earth contained any significant mass(es) of elements denser than iron and nickel, namely the white (appearance) precious metals (and a few others) except silver, specifically the siderophile elements, then these would necessarily have differentiated to the very center of the core into concentric nested spheres by planetary differentiation, with the most dense (and stable, i.e. platinum, iridium, and osmium, (etc.) in order of density) of these forming the innermost spheroid(s).[12] While unstable elements of such trans-iron/nickel density would have mostly decayed to iron/nickel/lead by the time the earth formed a discrete core.
See also: Densities of the elements (data page)
It then necessarily follows that all, or almost all, of these denser elements we have mined (or are even able to) at the surface (or near surface, or even at all "above" the core) have been delivered later as part of impact objects/masses.[13] "